Upcoming activities are currently disturbed by the COVID-19 pandemic.

Annual Meeting – Analog edition in Iceland

The Annual Meeting 2020 should have been in Iceland, but was transferred to a digital platform due to the COVID-19 pandemic. We hoped to postpone it to 2021 but that will not happen either. However we do not give up hope, and we will go to Iceland when the pandemic is over.

Winter School 2021

22nd – 24th November 2021, University of Oslo 🇳🇴

NordCO2 is collaborating with the ITN CO2PERATE to organise the 2021 Winter School, which will take place over the course of three days from the 22nd to the 24th of November this year. The focus of the school will be on the “Mechanisms of CO2 activation” as well as “Isotopic labelling”. The course will consist of digital lectures in the mornings and practical sessions in the  afternoon.

Monthly Seminars

The NordCO2 Monthly Seminars is a series of lectures by experts in the fields relevant to the NordCO2 consortium as well as student talks about their recently published works. The seminars are organised each month by a different institution from the NordCO2 consortium, and the lectures are often accessible to the public.

January 2021February 2021March 2021April 2021May 2021June 2021
No seminarNo seminar
July 2021August 2021September 2021October 2021November 2021December 2021
No seminarNo seminar

March 2021: Uppsala University 🇸🇪

1st March 2021, 13:00 CET, Zoom meeting

Lecture by Pr. Marc Robert from the REACTE group at the Laboratoire d’Électrochimie Moléculaire of Université Paris Diderot, France.

Title of the lecture:
“Molecular (photo)electrochemical Reduction of CO2 with Co and Fe Complexes.
Hybrid Catalysis, Highly Reduced Products”

 

Abstract:

Reduction of carbon dioxide has as main objective the production of useful organic compounds and fuels – renewable fuels – in which solar energy would be stored. Molecular catalysts can be employed to reach this goal. They may in particular provide excellent selectivity thanks to easy tuning of the electronic properties at the metal and of the ligand second and third coordination sphere. Recently it has been shown that such molecular catalysts may also be tuned for generating highly reduced products (beyond CO and formate), leading to new exciting advancements.

Hybridization of these catalysts with conductive or semi-conductive materials may lead to enhance stability and new catalytic properties, as well as inclusion of molecular catalysts in devices for applications. This approach bridges between homogeneous and heterogeneous, and it raises new fundamental questions that may further lead to breakthrough in CO2 reduction chemistry.

Our recent results in these various areas will be discussed.

References:

  1. E. Boutin, M. Robert, Trends in Chemistry, 2021, in press.
  2. P. B. Pati, E. Boutin, R. Wang, S. Diring, S. Jobic, N. Barreau, F. Odobel, M. Robert, Nat. Commun. 2020, 11:3499.
  3. B. Ma, G. Chen, C. Fave, L. Chen, R. Kuriki, K. Maeda, O. Ishitani, T-C. Lau, J. Bonin, M. Robert,  Am. Chem. Soc. 2020, 142, 6188-6195.
  4. S. Ren, D. Joulie, D. Salvatore, K. Torbensen, M. Wang, M. Robert, C. Berlinguette, Science 2019, 365, 367-369.
  5. E. Boutin, M. Wang, J. C. Lin, M. Mesnage, D. Mendoza, B. Lassalle-Kaiser, C. Hahn, T. F. Jaramillo, M. Robert, Angew. Chem. Int. Ed. 2019, 58, 16172-16176.
  6. Z. Guo, C. Cometto, G. Chen, L. Chen, B. Ma, H. Fan, T. Groizard, W-L. Man, S-M. Yiu, K-C. Lau, T-C. Lau, M. Robert, Nat. Catal. 2019, 2, 801-808.

 

Talk by NordCO2 PhD student Simon S. Perdersen from the Interdisciplinary Nanoscience Center at Aarhus University, Denmark.

This talk is reserved for the NordCO2 members and is accessed via Gather.

 

 

 

 

April 2021: Helsinki University 🇫🇮

28th April 2021, 09:00 CET

Lecture by Prof. Matthias Beller, Head of the Department of Applied Homogeneous Catalysis at the Liebniz-Institut für Katalyse (LIKAT), Germany.

Title of the lecture:
“Unifying Concepts for the Development of Catalysts for Small Molecule Activation”

 

 

 

28th April 2021, 10:00 CET

Presentation of the 9 research groups part of the C1 Value Programme from the Academy of Finland.

 

 

 

28th April 2021, 12:00 CET

Lecture by Prof. Walter Leitner, Director of the Division of Molecular Catalysis at the Max Planck Institute for Chemical Energy Conversion, Germany.

Title of the lecture:
“Power-to-X catalytic conversion of carbon dioxide and hydrogen for fuels and chemicals”

 

May 2021: University of Oslo  🇳🇴


20th May 2021, 14:00 CET

Lecture by Dr. Aleix Comas-Vives from the Modelling of Heterogeneous Catalysts research group at Universitat Autònoma de Barcelona, Spain.

Title of the lecture:
“Theory-Aided Comprehension of CO2 Conversion on Heterogeneous Catalysts”

 

 

 

Abstract:

A transition using sustainable energy sources requires the replacement of fossil-based fuels by
synthetic energy vectors. The conversion of CO2 to generate high-energy-density
(oxy)hydrocarbons catalyzed by heterogeneous catalysts is one of the most attractive routes for
this purpose since such materials are highly active in related CO2/CO conversion reactions.
Theoretical calculations are crucial to understanding heterogeneous catalysts at the atomic
level. This talk will provide an overview of our recent works in the field in thermally promoted
CO2/CO conversions,1-7 highlighting the activity of 2D-Mo2CTx (MXenes)6 and Cu single sites
supported on them (Cu@Mo2CTx).7 Theoretical calculations reveal that Cu@Mo2CTx enables
the simultaneous H2 heterolytic cleavage and C-H bond formation steps. We suggest this is due
to the electronic nature of Cu single sites and the oxyphilic character of the support.7

References:
1. K. Larmier, W. C. Liao, S. Tada, E. Lam, R. Verel, A. Bansode, A. Urakawa, A. Comas-Vives*, C.
Copéret*, Angew. Chem. Int. Ed. 2017, 56, 2318-2323.
2. E. Lam, J. J. Corral-Pérez, K. Larmier, G. Noh, P. Wolf, A. Comas-Vives, A. Urakawa, C. Copéret*,
Angew. Chem. Int. Ed. 2019, 131, 14127-14134.
3. M. Silaghi, A. Comas-Vives,* C. Copéret, ACS Catal. 2016, 6, 4501-4505.
4. L. Foppa, M. Silaghi, K. Larmier, A. Comas-Vives*, J. Catal. 2016, 343, 196-207.
5. L. Foppa, T. Margossian, S. M. Kim, C. Müller, C. Copéret, K. Larmier,* A. Comas-Vives* J. Am.
Chem. Soc. 2017, 139, 17128-17139.
6. Kurlov, A.; Deeva, E. B.; Abdala, P. M.; Lebedev, D.; Tsoukalou, A.; Comas-Vives, A.; Fedorov, A.;
Müller, C. R., Nat. Commun. 2020, 11, 4920.
7. Zhou, H.; Chen, Z.; Díaz López, E.; Lam, E.; Tsoukalou, A.; Willinger, E.; Kuznetsov, D. A.; Mance,
D.; Kierzkowska, A.; Donat, F.; Abdala, P. M.; Comas-Vives, A.*; Copéret, C.*; Fedorov, A.*; Müller, C.
R.*, under revisions.

20th May 2021, 14:45 CET

 Talk by NordCO2 PhD student Ebrahim Tayyebi from Prof. Skúlason’s research group at the University of Iceland, Iceland.

 

 

 

 

June 2021: UiT The arctic university of Norway  🇳🇴

23rd June 2021, 14:00 CET

Lecture by NordCO2 Associated PI and Assoc. Prof. Nina Lock from the Department of Biological and Chemical Engineering at Aarhus University, Denmark.

Title of the lecture:

Metal-organic frameworks for electrocatalytic CO2 reduction

 

 

 

Abstract:

Metal-organic frameworks (MOFs) are materials consisting of metal ions connected via rigid organic ligands. MOFs exhibit permanent porosity and the exposed metal sites render MOFs promising candidates for catalysis. To date, a number of MOFs have been reported to be active for the electrocatalytic CO2 reduction reaction. While MOFs resemble single site catalysts, they show high activity relative to the metal content, but the application of MOFs in electrocatalysis is often limited by their intrinsic poor electronic conductivity. Moreover, MOFs often have lower thermal and chemical stabilities in comparison with e.g. the corresponding metal oxides.
In this talk, approaches to increasing the electrical conductivity will be presented. Moreover, the consequences of the lacking chemical stability on the structure and electrocatalytic performance will be discussed.

 

September 2021: KTH Royal Institute of Technology 🇸🇪

24th September 2021, 14:00 CET (Zoom meeting)

Lecture by Professor Julio Lloret-Fillol from the Institute of Chemical Research of Catalonia, Spain.

Title of the lecture:

“Well-Defined Catalysts for Reductive Transformations; From Solar Fuels to Fine Solar Chemicals”

 

 

 

Abstract:

One of the most appealing research areas is the mechanistic understanding of multi-electron multi-proton processes, which is a central part of activating small molecules such as CO2 and H2O.1 Further understanding of how these mechanisms operate is essential for developing effective catalysts for sustainable energy conversion and storage.2

During the presentation, we will mainly focus on well-defined metal complexes as model systems to gain mechanistic information on CO2 and H2O reduction.3-7 We will also disclose factors that could affect the catalytic activity and improve it, such as the effect of the light6 or inhibiting the formation of off-cycle reaction intermediates.7

References:

  1.  M. D. Kärkäs, O. Verho, E. V. Johnston, B. Åkermark Chem. Rev. 2014, 114, 11863.
  2. A. Dutta, A. M. Appel and W. J. Shaw, Nat Rev Chem 2018, 2, 244.
  3. Franco, F.; Fernandez, S.; Lloret-Fillol, J. Curr. Opin. electrochemistry 2019, 15, 109
  4. F. Franco, M.F. Pinto, B. Royo, J. Lloret-Fillol Angew. Chem. Int. Ed. 2018, 57, 4603
  5. a) A. Call, Z. Codolà, F. Acuña-Parés, J. Lloret-Fillol, Chem. Eur. J. 2014, 20, 6171; b) A. Call, F. Franco, N. Kandoth, S. Fernández, M. González-Béjar, J. Pérez-Prieto, J.M. Luis, J. Lloret-Fillol Chem. Sci. 2018, 9, 2609; c) A. Call, C. Casadevall, F. Acuña-Pares, A. Casitas Montero, J. Lloret Fillol, Chem. Sci. 2017, 8, 4739-4749.
  6. a) Fernández, S.; Franco, F.; Casadevall, C.; Martin-Diaconescu, V.; Luis, J.M.; Lloret-Fillol, J. J. Am. Chem. Soc. 2020, 142, 120. b) Fernández, S.; Cañellas, S.; Franco, F.; Luis, J. M.; Pericàs, M. A.; Lloret-Fillol, J ChemElectroChem 2021, DOI: 10.1002/celc.202100859
  7. Dubed Bandomo, G. C.; et al ACS Catal. 2021, 11, 7210

Register here!

October 2021: University of Bergen  🇳🇴
November 2021: Stockholm University 🇸🇪
December 2021: University of Iceland 🇮🇸

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