For individual publications of participating researchers see their hompages (under PIs).
Annual Reports
Articles
| Luthra, Mahika; Castro, Abril C.; Balcells, David; Daasbjerg, Kim;Nova, Ainara. Metal-Dependent Mechanism of the Electrocatalytic Reduction of CO2 by Bipyridine Complexes Bearing Pendant Amines: A DFT Study. ACS Organic & Inorganic Au, 2024,. DOI: 10.1021/acsorginorgau.4c00046 |
| Phan, Ha; Gueret, Robin; Martínez-Pardo, Pablo; Valiente, Alejandro; Jaworski, Aleksander; Slabon, Adam; Martín-Matute, Belén. Synthesis of Benzoic Acids from Electrochemically Reduced CO2 Using Heterogeneous Catalysts. ChemSusChem, 2024, e202401084. DOI: 10.1002/cssc.202401084 |
| Sannes, Dag Kristian; Pulumati, Sri Harsha; Skulason, Egill; Nova, Ainara; Olsbye, Unni. CO2 hydrogenation to methanol over Pt functionalized Hf-UiO-67 versus Zr-UiO-67. Philosophical Transactions of the Royal Society A, 2024, 38220230269. DOI: 10.1098/rsta.2023.0269 |
| Pavlovic, Ljiljana; Carvalho, Bjorn; Hopmann, Kathrin H.. Revisiting the Mechanism of Asymmetric Ni-Catalyzed Reductive Carbo-Carboxylation with CO2: The Additives Affect the Product Selectivity. Chemistry – A European Journal, 2024, 30, e202401631. DOI: 10.1002/chem.202401631 |
| Gahlawat, Sahil; Artelsmair, Markus; Castro, Abril C.; Norrby, Per-Ola; Hopmann, Kathrin H.. Computational Study of the Ir-Catalyzed Formation of Allyl Carbamates from CO2. Organometallics, 2024, 43(17), 1818-1826. DOI: 10.1021/acs.organomet.4c00177 |
| Ding, Yuxuan; Pedersen, Simon S.; Wang, Yixian; Xiao, Han; Ball, Zachary T.. Ex Situ Gaseous Reagent for Multicomponent Amine Bioconjugation. Organic Letters, 2024, 26(31), 6608-6613. DOI: 10.1021/acs.orglett.4c02246 |
| Ding, Yuxuan; Pedersen, Simon S.; Wang, Haofan; Xiang, Baorui; Wang, Yixian; Yang, Zhi; Gao, Yuxiang; Morosan, Emilia; Jones, Matthew R.; Xiao, Han; Ball, Zachary T.. Selective Macrocyclization of Unprotected Peptides with an Ex Situ Gaseous Linchpin Reagent. Angewandte Chemie International Edition, 2024, 63(30), e202405344. DOI: 10.1002/anie.202405344 |
| Elliott, Todd; Charbonneau, Luc; Gazagnaire, Eva; Kilpelainen, Ilkka; Kotai, Bianka; Laczko, Gergely; Papai, Imre; Repo, Timo. Synergetic effects on the capture and release of CO2 using guanidine and amidine superbases. RCS Sustainability, 2024,2, 1753-1760. DOI: 10.1039/D4SU00022F |
| Pettersen, Martin; Do, Cuong Dat; Gorantla, Sai Manoj N. V. T.; Obst, Marc F.; Damm, Roman; Putra, Anggi E.; Gevorgyan, Ashot; Pavlovic, Ljiljana; Hopmann, Kathrin H.; Bayer, Annette. Asymmetric Boracarboxylation of Styrenes Using Carbon Dioxide. Advanced Synthesis & Catalysis, 2024,366, 2976. DOI: 10.1002/adsc.202301285 |
| Batista, Gabriel M. F.; Ebenbauer, Ruth; Day, Craig; Bergare, Jonas; Neumann, Karoline T.; Hopmann, Kathrin H.; Elmore, Charles S.; Rosas-Hernandez, Alonso; Skrydstrup, Troels. Efficient palladium-catalyzed electrocarboxylation enables late-stage carbon isotope labelling. Nature Communications, 2024,15, 2592. DOI: 10.1038/s41467-024-46820-9 |
| Davies, Jacob; Lyonnet, Julien R.; Carvalho, Bjorn; Sahoo, Basudev; Day, Craig S.; Julia-Hernandez, Francisco; Duan, Yaya; Velasco-Rubio, Alvaro; Obst, Marc; Norrby, Per-Ola; Hopmann, Kathrin H.; Martin, Ruben. Kinetically-Controlled Ni-Catalyzed Direct Carboxylation of Unactivated Secondary Alkyl Bromides without Chain Walking. Journal of the American Chemical Society, 2024,146, 3, 1753–1759. DOI: 10.1021/jacs.3c11205 |
| Pulumati, Sri Harsha; Sannes, Dag Kristian; Jabbour, Christia R.; Mandemaker, Laurens D. B.; Weckhuysen, Bert M.; Olsbye, Unni; Nova, Ainara; Skúlason, Egill. Mechanistic Insights in the Catalytic Hydrogenation of CO2 over Pt Nanoparticles in UiO-67 Metal-Organic Frameworks. ACS Catalysis, 2024, 14(1), 382-394. DOI: 10.1021/acscatal.3c03401 |
| Sun, Hongwei; Ahrens, Alexander; Martins Ferreira Batista, Gabriel; Donslund, Bjarte S.; Ravn, Anne K.; Schwibinger, Emil Vincent; Nova, Ainara; Skrydstrup, Troels. Solvent–base mismatch enables the deconstruction of epoxy polymers and bisphenol A recovery. Green Chemistry, 2024,26, 815-824. DOI: 10.1039/D3GC03707J |
| Pavlovic, Ljiljana; Hopmann, Kathrin H.. Understanding the Influence of Lewis Acids on CO2 Hydrogenation: The Critical Effect Is on Formate Rotation. Organometallics, 2023, 42(20), 3025–3035. DOI: 10.1021/acs.organomet.3c00342 |
| Bai, Yunfei; Taarning, Esben: Luthra, Mahika; Lundegaard, Lars F.; Katerinopoulou, Anna; Falsig, Hanne; Nova, Ainara; Martinez-Espin, Juan S.. Tracking Lattice Distortion Induced by Defects and Framework Tin in Beta Zeotypes. Journal of Physical Chemistry C, 2023, 127(38), 19278-19289. DOI: 10.1021/acs.jpcc.3c04751 |
| Kolodiazhnaia, Julia V.; Gudmundsson, Haraldur G.; Pedersen, Simon S.; Skrydstrup, Troels. Ex-Situ Generation of Bis(trifluoromethyl)disulfide and Applications to Trifluoromethylthiolation Reactions. European Journal of Organic Chemistry, 2024, 26(44), e202300843. DOI: 10.1002/ejoc.202300843 |
| Day, Craig S.: Ton, Stephanie J.; Kaussler, Clemens; Hoffmann, Daniel Vrønning; Skrydstrup, Troels. Low Pressure Carbonylation of Benzyl Carbonates and Carbamates for Applications in 13C Isotope Labeling and Catalytic CO2 Reduction Angewandte Chemie International Edition, 2023, 62(35), e202308238. DOI: 10.1002/anie.202308238 |
| Diesel, Anthony P.; Gahlawat, Sahil; Hazari, Nilay; Hopmann, Kathrin H.; Mercado, Brandon Q.. Comparative study of CO2 insertion into pincer supported palladium alkyl and aryl complexes. Chemical Science, 2023, 14, 8164-8179. DOI: 10.1039/D3SC01459B |
| Agarwala, Hemlata; Chen, Xiaoyu; Lyonnet, Julien R.; Johnson, Ben A.; Ahlquist, Mårten; Ott, Sascha. Alternating Metal-Ligand Coordination Improves Electrocatalytic CO2 Reduction by a Mononuclear Ru Catalyst. Angewandte Chemie International Edition, 2023, 62(17), e202218728. DOI: 10.1002/anie.202218728 |
| Ton, Stephanie J.; Ravn, Anne K.; Hoffmann, Daniel Vrønning; Day, Craig S.; Kingston, Lee; Elmore, Charles S.; Skrydstrup, Troels. Rapid Access to Carbon-Isotope-Labeled Alkyl and Aryl Carboxylates Applying Palladacarboxylates. JACS Au, 2023, 3(3), 756-761. DOI: 10.1021/jacsau.2c00708 |
| Sahari, Aleksi; Puumi, Jukka; Mannisto, Jere K.; Repo, Timo. Dual Nickel Photocatalysis for O-Aryl Carbamate Synthesis from Carbon Dioxide. The Journal of Organic Chemistry, 2023, 88(6), 3822–3829. DOI: 10.1021/acs.joc.3c00023 |
| Corneliussen, Nicklas Pham; Grove, Ebbe Klit; Schøler, Anne-Sofie Oxfeldt; Andersen, Anton; Donslund, Aske Skyum; Neumann, Karoline Thorum; Skrydstrup, Troels. Nickel-Catalyzed Carbonylative Coupling of Alkylzinc Reagents and α-Bromo-α,α-difluoroacetamides. Synlett, 2023, 34(12), 1452-1456. DOI: 10.1055/a-2036-4809 |
| Hong, Wanwan; Luthra, Mahika; Jakobsen, Joakim B.; Madsen, Monica R.; Castro, Abril C.; Hammershøj, Hans Christian D.; Pedersen, Steen U.; Balcells, David; Skrydstrup, Troels; Daasbjerg, Kim; Nova, Ainara. Exploring the Parameters Controlling Product Selectivity in Electrochemical CO2 Reduction in Competition with Hydrogen Evolution Employing Manganese Bipyridine Complexes. ACS Catalysis, 2023, 13(5), 3109–3119. DOI: 10.1021/acscatal.2c05951 |
| Hammershøj, Hans Christian D.; Gudmundsson, Haraldur G.; Kjærsgaard, Samuel; Bønnelykke, Jonas; Kolodiazhnaia, Julia; Skrydstrup, Troels. Multi-carbon labelling of active pharmaceutical ingredients enabled by a three-gas surrogate hydroformylation. Nature Synthesis, 2023, 2(3), 243-250. DOI: 10.1038/s44160-022-00223-0 |
| Neumann, Karoline T.; Ravn, Anne K.; Johansen, Martin B.; Donslund, Aske S.; Rønne, Magnus H.; Gudmundsson, Haraldur G.; Skrydstrup, Troels. Reduction of CO2 to CO and Their Applications. The Chemical Transformations of C1 Compounds, 2022,, 1027-1072. DOI: 10.1002/9783527831883.ch24 |
| Rodríguez-Jiménez, Santiago; Song, Hongwei; Lam, Erwin; Wright, Demelza; Pannwitz, Andrea; Bonke, Shannon A.; Baumberg, Jeremy J.; Bonnet, Sylvestre; Hammarström, Leif; Reisner, Erwin. Self-Assembled Liposomes Enhance Electron Transfer for Efficient Photocatalytic CO2 Reduction. Journal of the American Chemical Society, 2022, 144(21), 9399-9412. DOI: 10.1021/jacs.2c01725 |
| Mendelsohn, Lauren N.; Pavlovic, Ljiljana; Zhong, Hongyu; Friedfeld, Max R.; Shevlin, Michael; Hopmann, Kathrin H.; Chirik, Paul J.. Mechanistic Investigations of the Asymmetric Hydrogenation of Enamides with Neutral Bis(phosphine) Cobalt Precatalysts. Journal of the American Chemical Society, 2022, 144(34), 15764-15778. DOI: 10.1021/jacs.2c06454 |
| Pavlovic, Ljiljana; Mendelsohn, Lauren N.; Zhong, Hongyu; Chirik, Paul J.; Hopmann, Kathrin H.. Cobalt-Catalyzed Asymmetric Hydrogenation of Enamides: Insights into Mechanisms and Solvent Effects. Organometallics, 2022, 41(14), 1872-1882. DOI: 10.1021/acs.organomet.2c00180 |
| Ding, Yuxuan; Pedersen, Simon S.; Lin, Alex; Qian, Ruoyu; Ball, Zachary T.. Direct formation and site-selective elaboration of methionine sulfoximine in polypeptides. Chemical Science, 2022, 13(47), 14101-14105. DOI: 10.1039/D2SC04220G |
| Gevorgyan, Ashot; Hopmann, Kathrin H.; Bayer, Annette. Improved Buchwald-Hartwig Amination by the Use of Lipids and Lipid Impurities. Organometallics, 2022, 41(14), 1777-1785. DOI: 10.1021/acs.organomet.1c00517 |
| Castner, Ashleigh T.; Su, Hao; Svensson Grape, Erik; Inge, A. Ken; Johnson, Ben A.; Ahlquist, Mårten S. G.; Ott, Sascha. Microscopic Insights into Cation-Coupled Electron Hopping Transport in a Metal-Organic Framework. Journal of the American Chemical Society, 2022, 144(13), 5910-5920. DOI: 10.1021/jacs.1c13377 |
| Day, Craig S.; Do, Cuong Dat; Odena, Carlota; Benet-Buchholz, Jordi; Xu, Liang; Foroutan-Nejad, Cina; Hopmann, Kathrin H.; Martin, Ruben. Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction. Journal of the American Chemical Society, 2022, 144(29), 13109-13117. DOI: 10.1021/jacs.2c01807 |
| García-Vázquez, Víctor; Carretero Cerdán, Alba; Sanz-Marco, Amparo; Gómez-Bengoa, Enrique; Martín-Matute, Belén. An Expedient Method for the Umpolung Coupling of Enols with Heteronucleophiles. Chemistry – A European Journal, 2022, 28(44), e202201000. DOI: 10.1002/chem.202201000 |
| Gedde, Oliver R.; Bonde, Andreas; Golbækdal, Peter I.; Skrydstrup, Troels. Pd-Catalyzed Difluoromethylations of Aryl Boronic Acids, Halides, and Pseudohalides with ICF2H Generated ex Situ. Chemistry – A European Journal, 2022, 28(34), e202200997. DOI: 10.1002/chem.202200997 |
| Sahari, Aleksi; Do, Cuong Dat; Mannisto, Jere K.; Antico, Emanuele; Amaratunga, Angelo; Hopmann, Kathrin H.; Repo, Timo. Titanium isopropoxide-mediated cis-selective synthesis of 3,4-substituted butyrolactones from CO2. Chemical Communications, 2022, 58, 3027-3030. DOI: 10.1039/D2CC00446A |
| Deziel, Anthony P.; Espinosa, Matthew R.; Pavlovic, Ljiljana; Charboneau, David J.; Hazari, Nilay; Hopmann, Kathrin H.; Mercado, Brandon Q.. Ligand and solvent effects on CO2 insertion into group 10 metal alkyl bonds. Chemical Science, 2022, 13, 2391-2404. DOI: 10.1039/D1SC06346D |
| Gevorgyan, Ashot; Hopmann, Kathrin H.; Bayer, Annette. Lipids as versatile solvents for chemical synthesis. Green Chemistry, 2021, 23(18), 7219-7227. DOI: 10.1039/D1GC02311J |
| Ton, Stephanie J.; Neumann, Karoline T.; Nørby, Peter; Skrydstrup, Troels. Nickel-Mediated Alkoxycarbonylation for Complete Carbon Isotope Replacement. Journal of the American Chemical Society, 2021, 143(42), 17816-17824. DOI: 10.1021/jacs.1c09170 |
| Madsen, Monica R.; Rønne, Magnus H.; Heuschen, Marvin; Golo, Dusanka; Ahlquist, Mårten S. G.; Skrydstrup, Troels; Pedersen, Steen U.; Daasbjerg, Kim. Promoting Selective Generation of Formic Acid from CO2 Using Mn(bpy)(CO)3Br as Electrocatalyst and Triethylamine/Isopropanol as Additives. Journal of the American Chemical Society, 2021, 143(48), 20491-20500. DOI: 10.1021/jacs.1c10805 |
| Ton, Stephanie J.; Neumann, Karoline T.; Nørby, Peter; Skrydstrup, Troels. Nickel-Mediated Alkoxycarbonylation for Complete Carbon Isotope Replacement. Journal of the American Chemical Society, 2021, 143(42), 17816-17824. DOI: 10.1021/jacs.1c09170 |
| Artús Suárez, Lluís; Balcells, David; Nova, Ainara. Computational Studies on the Mechanisms for Deaminative Amide Hydrogenation by Homogeneous Bifunctional Catalysts. Topics in Catalysis, 2021, (), . DOI: 10.1007/s11244-021-01542-w |
| Madsen, Monica R.; Rønne, Magnus H.; Heuschen, Marvin; Golo, Dusanka; Ahlquist, Mårten S. G.; Skrydstrup, Troels; Pedersen, Steen U.; Daasbjerg, Kim. Promoting Selective Generation of Formic Acid from CO2 Using Mn(bpy)(CO)3Br as Electrocatalyst and Triethylamine/Isopropanol as Additives. Journal of the American Chemical Society, 2021, 143(48), 20491-20500. DOI: 10.1021/jacs.1c10805 |
| Atrak, Narges; Tayyebi, Ebrahim; Skúlason, Egill. Effect of co-adsorbed water on electrochemical CO2 reduction reaction on transition metal oxide catalysts. Applied Surface Science, 2021, 570(), 151031. DOI: 10.1016/j.apsusc.2021.151031 |
| Queyriaux, Nicolas; Esmieu, Charlène; Gupta, Arvind K.; Vendier, Laure; Ott, Sascha; Orio, Maylis; Hammarström, Leif. Electrochemical, Spectroscopic, and Computational Investigation of a Series of Polypyridyl Ruthenium(II) Complexes: Characterization of Reduced States. European Journal of Inorganic Chemistry, 2021, 2021(13), 1263-1270. DOI: 10.1002/ejic.202001165 |
| Mannisto, Jere K.; Pavlovic, Ljiljana; Tiainen, Tony; Nieger, Martin; Sahari, Aleksi; Hopmann, Kathrin H.; Repo, Timo. Mechanistic insights into carbamate formation from CO2 and amines: the role of guanidine-CO2 adducts. Catalysis Science & Technology, 2021, (), . DOI: 10.1039/D1CY01433A |
| Xu, Zheyuan; Liu, Deguang; Yu, Haizhu; Ahlquist, Mårten S. G.; Fu, Yao. Mechanistic study on the photo carboxylation of benzylic C-H bonds by xanthone and Ni(0) catalysts. Molecular Catalysis, 2021, 514(), 111785. DOI: 10.1016/j.mcat.2021.111785 |
| Jakobsen, Joakim B.; Rønne, Magnus H.; Daasbjerg, Kim; Skrydstrup, Troels. Are Amines the Holy Grail for Facilitating CO2 Reduction?. , 2021, (), . DOI: 10.1002/anie.202014255 |
| Pavlovic, Ljiljana; Pettersen, Martin; Gevorgyan, Ashot; Vaitla, Janakiram; Bayer, Annette; Hopmann, Kathrin H.. Computational and Experimental Insights into Asymmetric Rh-Catalyzed Hydrocarboxylation with CO2. European Journal of Organic Chemistry, 2021, 2021(4), 663-670. DOI: 10.1002/ejoc.202001469 |
| Pedersen, Simon S.; Donslund, Aske S.; Mikkelsen, Jesper H.; Bakholm, Oskar S.; Papp, Florian; Jensen, Kim B.; Gustafsson, Magnus B. F.; Skrydstrup, Troels. A Nickel(II)-Mediated Thiocarbonylation Strategy for Carbon Isotope Labeling of Aliphatic Carboxamides. Chemistry – A European Journal, 2021, 27(24), 7114-7123. DOI: 10.1002/chem.202005261 |
| Jia, Xiuwen; Kramer, Søren; Skrydstrup, Troels; Lian, Zhong. Design and Applications of a SO2 Surrogate in Palladium-Catalyzed Direct Aminosulfonylation between Aryl Iodides and Amines. Angewandte Chemie International Edition, 2021, 60(13), 7353-7359. DOI: 10.1002/anie.202014111 |
| Xu, Yuantai; Shao, Yifan; Ahlquist, Mårten S. G.; Yu, Haizhu; Fu, Yao. Pivotal Electron Delivery Effect of the Cobalt Catalyst in Photocarboxylation of Alkynes: A DFT Calculation. The Journal of Organic Chemistry, 2021, 86(2), 1540-1548. DOI: 10.1021/acs.joc.0c02393 |
| Laurans, Maxime; Wells, Jordann A. L.; Ott, Sascha. Immobilizing molecular Ru complexes on a protective ultrathin oxide layer of p-Si electrodes towards photoelectrochemical CO2 reduction. Dalton Transactions, 2021, (), . DOI: 10.1039/D1DT01331A |
| Rønne, Magnus H.; Madsen, Monica R.; Skrydstrup, Troels; Pedersen, Steen U.; Daasbjerg, Kim. Mechanistic Elucidation of Dimer Formation and Strategies for Its Suppression in Electrochemical Reduction of Fac-Mn(bpy)(CO)3Br. ChemElectroChem, 2021, 8(11), 2108-2114. DOI: 10.1002/celc.202100279 |
| Donslund, Aske S.; Pedersen, Simon S.; Gaardbo, Cecilie; Neumann, Karoline T.; Kingston, Lee; Elmore, Charles S.; Skrydstrup, Troels. Direct Access to Isotopically Labeled Aliphatic Ketones Mediated by Nickel(I) Activation. Angewandte Chemie International Edition, 2020, 59(21), 8099-8103. DOI: 10.1002/anie.201916391 |
| Rønne, Magnus H.; Cho, Dasol; Madsen, Monica R.; Jakobsen, Joakim B.; Eom, Seunghwan; Escoudé, Émile; Hammershøj, Hans Christian D.; Nielsen, Dennis U.; Pedersen, Steen U.; Baik, Mu-Hyun; Skrydstrup, Troels; Daasbjerg, Kim. Ligand-Controlled Product Selectivity in Electrochemical Carbon Dioxide Reduction Using Manganese Bipyridine Catalysts. Journal of the American Chemical Society, 2020, 142(9), 4265-4275. DOI: 10.1021/jacs.9b11806 |
| Artús Suárez, Lluís; Jayarathne, Upul; Balcells, David; Bernskoetter, Wesley H.; Hazari, Nilay; Jaraiz, Martín; Nova, Ainara. Rational selection of co-catalysts for the deaminative hydrogenation of amides. Chemical Science, 2020, 11(8), 2225-2230. DOI: 10.1039/C9SC03812D |
| Gutterød, Emil S.; Lazzarini, Andrea; Fjermestad, Torstein; Kaur, Gurpreet; Manzoli, Maela; Bordiga, Silvia; Svelle, Stian; Lillerud, Karl P.; Skúlason, Egill; Øien-Ødegaard, Sigurd; Nova, Ainara; Olsbye, Unni. Hydrogenation of CO2 to Methanol by Pt Nanoparticles Encapsulated in UiO-67: Deciphering the Role of the Metal-Organic Framework. Journal of the American Chemical Society, 2020, 142(2), 999-1009. DOI: 10.1021/jacs.9b10873 |
| Madsen, Monica R.; Jakobsen, Joakim B.; Rønne, Magnus H.; Liang, Hongqing; Hammershøj, Hans Christian D.; Nørby, Peter; Pedersen, Steen U.; Skrydstrup, Troels; Daasbjerg, Kim. Evaluation of the Electrocatalytic Reduction of Carbon Dioxide using Rhenium and Ruthenium Bipyridine Catalysts Bearing Pendant Amines in the Secondary Coordination Sphere. Organometallics, 2020, 39(9), 1480-1490. DOI: 10.1021/acs.organomet.9b00815 |
| Obst, Marc F.; Gevorgyan, Ashot; Bayer, Annette; Hopmann, Kathrin H.. Mechanistic Insights into Copper-Catalyzed Carboxylations. Organometallics, 2020, 39(9), 1545-1552. DOI: 10.1021/acs.organomet.9b00710 |
| Gevorgyan, Ashot; Hopmann, Kathrin H.; Bayer, Annette. Exploration of New Biomass-Derived Solvents: Application to Carboxylation Reactions. ChemSusChem, 2020, 13(8), 2080-2088. DOI: 10.1002/cssc.201903224 |
| Gevorgyan, Ashot; Hopmann, Kathrin H.; Bayer, Annette. Formal C−H Carboxylation of Unactivated Arenes. Chemistry – A European Journal, 2020, 26(27), 6064-6069. DOI: 10.1002/chem.202000515 |
| Ismael, Aya; Skrydstrup, Troels; Bayer, Annette. Carbonylative Suzuki-Miyaura couplings of sterically hindered aryl halides: synthesis of 2-aroylbenzoate derivatives. Organic & Biomolecular Chemistry, 2020, 18(9), 1754-1759. DOI: 10.1039/D0OB00044B |
| Queyriaux, N.; Abel, K.; Fize, J.; Pécaut, J.; Orio, M.; Hammarström, L.. From non-innocent to guilty: on the role of redox-active ligands in the electro-assisted reduction of CO2 mediated by a cobalt(II)-polypyridyl complex. Sustainable Energy & Fuels, 2020, 4(7), 3668-3676. DOI: 10.1039/D0SE00570C |
| Johansen, Martin B.; Gedde, Oliver R.; Mayer, Thea S.; Skrydstrup, Troels. Access to Aryl and Heteroaryl Trifluoromethyl Ketones from Aryl Bromides and Fluorosulfates with Stoichiometric CO. Organic Letters, 2020, 22(11), 4068-4072. DOI: 10.1021/acs.orglett.0c01117 |
| Tayyebi, Ebrahim; Hussain, Javed; Skúlason, Egill. Why do RuO2 electrodes catalyze electrochemical CO2 reduction to methanol rather than methane or perhaps neither of those?. Chemical Science, 2020, 11(35), 9542-9553. DOI: 10.1039/D0SC01882A |
| de Gracia Triviño, Juan Angel; Ahlquist, Mårten S. G.. Oxide Relay: An Efficient Mechanism for Catalytic Water Oxidation at Hydrophobic Electrode Surfaces. The Journal of Physical Chemistry Letters, 2020, 11(17), 7383-7387. DOI: 10.1021/acs.jpclett.0c02009 |
| Pedersen, Samuel K.; Gudmundsson, Haraldur G.; Nielsen, Dennis U.; Donslund, Bjarke S.; Hammershøj, Hans Christian D.; Daasbjerg, Kim; Skrydstrup, Troels. Main element chemistry enables gas-cylinder-free hydroformylations. Nature Catalysis, 2020, 3(10), 843-850. DOI: 10.1038/s41929-020-00510-z |
| Gutterød, Emil Sebastian; Pulumati, Sri Harsha; Kaur, Gurpreet; Lazzarini, Andrea; Solemsli, Bjørn Gading; Gunnæs, Anette Eleonora; Ahoba-Sam, Christian; Kalyva, Maria Evangelou; Sannes, Johnny Andreas; Svelle, Stian; Skúlason, Egill; Nova, Ainara; Olsbye, Unni. Influence of Defects and H2O on the Hydrogenation of CO2 to Methanol over Pt Nanoparticles in UiO-67 Metal-Organic Framework. Journal of the American Chemical Society, 2020, 142(40), 17105-17118. DOI: 10.1021/jacs.0c07153 |
| Somerville, Rosie J.; Odena, Carlota; Obst, Marc F.; Hazari, Nilay; Hopmann, Kathrin H.; Martin, Ruben. Ni(I)-Alkyl Complexes Bearing Phenanthroline Ligands: Experimental Evidence for CO2 Insertion at Ni(I) Centers. Journal of the American Chemical Society, 2020, 142(25), 10936-10941. DOI: 10.1021/jacs.0c04695 |
| Li, Xiong; Xu, Jie; Li, Yue; Kramer, Søren; Skrydstrup, Troels; Lian, Zhong. Silylcarboxylic Acids as Bifunctional Reagents: Application in Palladium-Catalyzed External-CO-Free Carbonylative Cross-Coupling Reactions. Advanced Synthesis & Catalysis, 2020, 362(19), 4078-4083. DOI: 10.1002/adsc.202000586 |
| Ravn, Anne K.; Johansen, Martin B.; Skrydstrup, Troels. Controlled Release of Reactive Gases: A Tale of Taming Carbon Monoxide. ChemPlusChem, 2020, 85(7), 1529-1533. DOI: 10.1002/cplu.202000319 |
| Nie, Wan; Shao, Yifan; Ahlquist, Mårten S. G.; Yu, Haizhu; Fu, Yao. Mechanistic study on the regioselective Ni-catalyzed dicarboxylation of 1,3-dienes with CO2. Organic Chemistry Frontiers, 2020, 7(24), 4080-4088. DOI: 10.1039/D0QO01173H |
| Ismael, Aya; Gevorgyan, Ashot; Skrydstrup, Troels; Bayer, Annette. Renewable Solvents for Palladium-Catalyzed Carbonylation Reactions. Organic Process Research & Development, 2020, 24(11), 2665-2675. DOI: 10.1021/acs.oprd.0c00325 |
| García-López, Diego; Pavlovic, Ljiljana; Hopmann, Kathrin H.. To Bind or Not to Bind: Mechanistic Insights into C-CO2 Bond Formation with Late Transition Metals. Organometallics, 2020, 39(8), 1339-1347. DOI: 10.1021/acs.organomet.0c00090 |
| Domino, Katrine; Johansen, Martin B.; Daasbjerg, Kim; Skrydstrup, Troels. Stoichiometric Studies on the Carbonylative Trifluoromethylation of Aryl Pd(II) Complexes using TMSCF3 as the Trifluoromethyl Source. Organometallics, 2020, 39(5), 688-697. DOI: 10.1021/acs.organomet.9b00849 |
| Chen, Xiaoyu; Hu, Xin-Ming; Daasbjerg, Kim; Ahlquist, Mårten S. G.. Understanding the Enhanced Catalytic CO2 Reduction upon Adhering Cobalt Porphyrin to Carbon Nanotubes and the Inverse Loading Effect. Organometallics, 2020, 39(9), 1634-1641. DOI: 10.1021/acs.organomet.9b00726 |
| Chen, Xiaoyu; Ahlquist, Mårten S. G.. Deconstructing the Enhancing Effect on CO2 Activation in the Electric Double Layer with EVB Dynamic Reaction Modeling. The Journal of Physical Chemistry C, 2020, 124(41), 22479-22487. DOI: 10.1021/acs.jpcc.0c05974 |
| Niemi, Teemu; Repo, Timo. Antibiotics from Carbon Dioxide: Sustainable Pathways to Pharmaceutically Relevant Cyclic Carbamates. European Journal of Organic Chemistry, 2019, 2019(6), 1180-1188. DOI: 10.1002/ejoc.201801598 |
| Vaitla, Janakiram; Bayer, Annette; Hopmann, Kathrin H.. Vinyl Sulfoxonium Ylide: A New Vinyl Carbenoid Transfer Reagent for the Synthesis of Heterocycles. Synlett, 2019, 30(12), 1377-1383. DOI: 10.1055/s-0037-1611771 |
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| Queyriaux, Nicolas; Swords, Wesley B.; Agarwala, Hemlata; Johnson, Ben A.; Ott, Sascha; Hammarström, Leif. Mechanistic insights on the non-innocent role of electron donors: reversible photocapture of CO2 by RuII-polypyridyl complexes. Dalton Transactions, 2019, 48(45), 16894-16898. DOI: 10.1039/C9DT03461G |
| Xin, Zhuo; Skrydstrup, Troels. Liquid Marbles: A Promising and Versatile Platform for Miniaturized Chemical Reactions. Angewandte Chemie International Edition, 2019, 58(35), 11952-11954. DOI: 10.1002/anie.201905204 |
| Ravn, Anne K.; Vilstrup, Maria B. T.; Noerby, Peter; Nielsen, Dennis U.; Daasbjerg, Kim; Skrydstrup, Troels. Carbon Isotope Labeling Strategy for β-Amino Acid Derivatives via Carbonylation of Azanickellacycles. Journal of the American Chemical Society, 2019, 141(30), 11821-11826. DOI: 10.1021/jacs.9b05934 |
| Collin, Hugo P.; Reis, Wallace J.; Nielsen, Dennis U.; Lindhardt, Anders T.; Valle, Marcelo S.; Freitas, Rossimiriam P.; Skrydstrup, Troels. COtab: Expedient and Safe Setup for Pd-Catalyzed Carbonylation Chemistry. Organic Letters, 2019, 21(15), 5775-5778. DOI: 10.1021/acs.orglett.9b01423 |
| Carrasco, Sergio; Sanz-Marco, Amparo; Martín-Matute, Belén. Fast and Robust Synthesis of Metalated PCN-222 and Their Catalytic Performance in Cycloaddition Reactions with CO2. Organometallics, 2019, 38(18), 3429-3435. DOI: 10.1021/acs.organomet.9b00273 |
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| Mannisto, Jere K.; Sahari, Aleksi; Lagerblom, Kalle; Niemi, Teemu; Nieger, Martin; Sztanó, Gábor; Repo, Timo. One-Step Synthesis of 3,4-Disubstituted 2-Oxazolidinones by Base-Catalyzed CO2 Fixation and Aza-Michael Addition. Chemistry – A European Journal, 2019, 25(44), 10284-10289. DOI: 10.1002/chem.201902451 |
| Gevorgyan, Ashot; Obst, Marc F.; Guttormsen, Yngve; Maseras, Feliu; Hopmann, Kathrin H.; Bayer, Annette. Caesium fluoride-mediated hydrocarboxylation of alkenes and allenes: scope and mechanistic insights. Chemical Science, 2019, 10(43), 10072-10078. DOI: 10.1039/C9SC02467K |
| Leischner, Thomas; Suarez, Lluis Artús; Spannenberg, Anke; Junge, Kathrin; Nova, Ainara; Beller, Matthias. Highly selective hydrogenation of amides catalysed by a molybdenum pincer complex: scope and mechanism. Chemical Science, 2019, 10(45), 10566-10576. DOI: 10.1039/C9SC03453F |
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| Pavlovic, Ljiljana; Vaitla, Janakiram; Bayer, Annette; Hopmann, Kathrin H.. Rhodium-Catalyzed Hydrocarboxylation: Mechanistic Analysis Reveals Unusual Transition State for Carbon-Carbon Bond Formation. Organometallics, 2018, 37(6), 941-948. DOI: 10.1021/acs.organomet.7b00899 |
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| Niemi, Teemu; Fernández, Israel; Steadman, Bethany; Mannisto, Jere K.; Repo, Timo. Carbon dioxide-based facile synthesis of cyclic carbamates from amino alcohols. Chemical Communications, 2018, 54(25), 3166-3169. DOI: 10.1039/C8CC00636A |
| Johnson, Ben A.; Bhunia, Asamanjoy; Fei, Honghan; Cohen, Seth M.; Ott, Sascha. Development of a UiO-Type Thin Film Electrocatalysis Platform with Redox-Active Linkers. Journal of the American Chemical Society, 2018, 140(8), 2985-2994. DOI: 10.1021/jacs.7b13077 |
| Huang, Jing; Gatty, Mélina Gilbert; Xu, Bo; Pati, Palas Baran; Etman, Ahmed S.; Tian, Lei; Sun, Junliang; Hammarström, Leif; Tian, Haining. Covalently linking CuInS2 quantum dots with a Re catalyst by click reaction for photocatalytic CO2 reduction. Dalton Transactions, 2018, 47(31), 10775-10783. DOI: 10.1039/C8DT01631C |
| Hu, Xin-Ming; Hval, Halvor Høen; Bjerglund, Emil Tveden; Dalgaard, Kirstine Junker; Madsen, Monica Rohde; Pohl, Marga-Martina; Welter, Edmund; Lamagni, Paolo; Buhl, Kristian Birk; Bremholm, Martin; Beller, Matthias; Pedersen, Steen Uttrup; Skrydstrup, Troels; Daasbjerg, Kim. Selective CO2 Reduction to CO in Water using Earth-Abundant Metal and Nitrogen-Doped Carbon Electrocatalysts. ACS Catalysis, 2018, 8(7), 6255-6264. DOI: 10.1021/acscatal.8b01022 |
| Marcos, Rocío; Bertini, Federica; Rinkevicius, Zilvinas; Peruzzini, Maurizio; Gonsalvi, Luca; Ahlquist, Mårten S. G.. Mechanistic Studies on NaHCO3 Hydrogenation and HCOOH Dehydrogenation Reactions Catalysed by a FeII Linear Tetraphosphine Complex. Chemistry – A European Journal, 2018, 24(20), 5366-5372. DOI: 10.1002/chem.201704927 |
| Vaitla, Janakiram; Guttormsen, Yngve; Mannisto, Jere K.; Nova, Ainara; Repo, Timo; Bayer, Annette; Hopmann, Kathrin H.. Enantioselective Incorporation of CO2: Status and Potential. ACS Catalysis, 2017, 7(10), 7231-7244. DOI: 10.1021/acscatal.7b02306 |
| Abdellah, Mohamed; El-Zohry, Ahmed M.; Antila, Liisa J.; Windle, Christopher D.; Reisner, Erwin; Hammarström, Leif. Time-Resolved IR Spectroscopy Reveals a Mechanism with TiO2 as a Reversible Electron Acceptor in a TiO2-Re Catalyst System for CO2 Photoreduction. Journal of the American Chemical Society, 2017, 139(3), 1226-1232. DOI: 10.1021/jacs.6b11308 |