{"id":1250,"date":"2020-03-11T17:20:45","date_gmt":"2020-03-11T16:20:45","guid":{"rendered":"https:\/\/site.uit.no\/nordco2\/?p=1250"},"modified":"2024-10-11T12:25:58","modified_gmt":"2024-10-11T10:25:58","slug":"new-article-by-the-skrudstrup-group","status":"publish","type":"post","link":"https:\/\/site.uit.no\/nordco2\/2020\/03\/11\/new-article-by-the-skrudstrup-group\/","title":{"rendered":"New article by the Skrudstrup group"},"content":{"rendered":"<p style=\"text-align: left\"><strong>Abstract<\/strong><br \/>\nCarbon dioxide utilization through electrocatalysis is a promising pathway toward a more sustainable future. In this work the electrocatalytic reduction of carbon dioxide by Re<sup>I<\/sup>\u00a0and Ru<sup>II<\/sup>\u00a0bipyridine complexes bearing pendant amines (<i>N<\/i>,<i>N<\/i>\u2032-(([2,2\u2032-bipyridine]-6,6\u2032-diylbis(2,1-phenylene))bis(methylene))bis(<i>N<\/i>-ethylethanamine) (dEAbpy)) is evaluated. In both cases, the major reduction product is carbon monoxide accompanied by some formic acid, although the yield of the latter never reaches the predominant level known from the corresponding Mn(dEAbpy)(CO)<sub>3<\/sub>Br complex. This demonstrates the profound effect of the identity of the metal center, in addition to the ligand, for the product distribution. In this work, we report the synthesis procedures and X-ray diffraction studies along with electrochemical and infrared spectroelectrochemical studies of Re(dEAbpy)(CO)<sub>3<\/sub>Cl and Ru(dEAbpy)(CO)<sub>2<\/sub>Cl<sub>2<\/sub>\u00a0to propose a mechanism for the CO<sub>2<\/sub>\u00a0reduction reaction.<br \/>\n<img fetchpriority=\"high\" decoding=\"async\" class=\"size-full wp-image-1251 aligncenter\" src=\"https:\/\/site.uit.no\/nordco2\/wp-content\/uploads\/sites\/344\/2020\/04\/om9b00815_0007.gif\" alt=\"\" width=\"500\" height=\"269\" \/><\/p>\n<p style=\"text-align: center\"><strong>Read at:<a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acs.organomet.9b00815\"><img decoding=\"async\" class=\"size-full wp-image-1236 aligncenter\" src=\"https:\/\/site.uit.no\/nordco2\/wp-content\/uploads\/sites\/344\/2020\/04\/acs_journal_logo.png\" alt=\"\" width=\"481\" height=\"82\" srcset=\"https:\/\/site.uit.no\/nordco2\/wp-content\/uploads\/sites\/344\/2020\/04\/acs_journal_logo.png 481w, https:\/\/site.uit.no\/nordco2\/wp-content\/uploads\/sites\/344\/2020\/04\/acs_journal_logo-300x51.png 300w, https:\/\/site.uit.no\/nordco2\/wp-content\/uploads\/sites\/344\/2020\/04\/acs_journal_logo-480x82.png 480w\" sizes=\"(max-width: 481px) 100vw, 481px\" \/><\/a><\/strong><\/p>\n<p>For a list of publications by the members of NordCO<sub>2<\/sub>, see our <a href=\"https:\/\/site.uit.no\/nordco2\/publications\/\">Publications<\/a> page!<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Abstract Carbon dioxide utilization through electrocatalysis is a promising pathway toward a more sustainable future. In this work the electrocatalytic reduction of carbon dioxide by &hellip;<\/p>\n","protected":false},"author":514,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"ngg_post_thumbnail":0,"footnotes":""},"categories":[8],"tags":[],"class_list":["post-1250","post","type-post","status-publish","format-standard","hentry","category-research"],"_links":{"self":[{"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/posts\/1250","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/users\/514"}],"replies":[{"embeddable":true,"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/comments?post=1250"}],"version-history":[{"count":2,"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/posts\/1250\/revisions"}],"predecessor-version":[{"id":1253,"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/posts\/1250\/revisions\/1253"}],"wp:attachment":[{"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/media?parent=1250"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/categories?post=1250"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/tags?post=1250"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}