{"id":1257,"date":"2020-01-14T17:28:40","date_gmt":"2020-01-14T16:28:40","guid":{"rendered":"https:\/\/site.uit.no\/nordco2\/?p=1257"},"modified":"2024-10-11T12:26:55","modified_gmt":"2024-10-11T10:26:55","slug":"new-article-from-the-hopmann-bayer-group","status":"publish","type":"post","link":"https:\/\/site.uit.no\/nordco2\/2020\/01\/14\/new-article-from-the-hopmann-bayer-group\/","title":{"rendered":"New article from the Hopmann\/Bayer group"},"content":{"rendered":"<p style=\"text-align: left\"><strong>Abstract<\/strong><br \/>\nA range of hitherto unexplored biomass\u2010derived chemicals have been evaluated as new sustainable solvents for a large variety of CO<sub>2<\/sub>\u2010based carboxylation reactions. Known biomass\u2010derived solvents (biosolvents) are also included in the study and the results are compared with commonly used solvents for the reactions. Biosolvents can be efficiently applied in a variety of carboxylation reactions, such as Cu\u2010catalyzed carboxylation of organoboranes and organoboronates, metal\u2010catalyzed hydrocarboxylation, borocarboxylation, and other related reactions. For many of these reactions, the use of biosolvents provides comparable or better yields than the commonly used solvents. The best biosolvents identified are the so far unexplored candidates isosorbide dimethyl ether, acetaldehyde diethyl acetal, rose oxide, and eucalyptol, alongside the known biosolvent 2\u2010methyltetrahydrofuran. This strategy was used for the synthesis of the commercial drugs Fenoprofen and Flurbiprofen.<br \/>\n<img decoding=\"async\" class=\"size-full wp-image-1259 aligncenter\" src=\"https:\/\/site.uit.no\/nordco2\/wp-content\/uploads\/sites\/344\/2020\/04\/ezgif.com-gif-maker-2.jpg\" alt=\"\" width=\"299\" height=\"85\" \/><\/p>\n<p style=\"text-align: center\"><strong>Read at:<a href=\"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full\/10.1002\/cssc.201903224\"><img fetchpriority=\"high\" decoding=\"async\" class=\"size-full wp-image-1260 aligncenter\" src=\"https:\/\/site.uit.no\/nordco2\/wp-content\/uploads\/sites\/344\/2020\/04\/ezgif.com-gif-maker-3.jpg\" alt=\"\" width=\"690\" height=\"80\" srcset=\"https:\/\/site.uit.no\/nordco2\/wp-content\/uploads\/sites\/344\/2020\/04\/ezgif.com-gif-maker-3.jpg 690w, https:\/\/site.uit.no\/nordco2\/wp-content\/uploads\/sites\/344\/2020\/04\/ezgif.com-gif-maker-3-300x35.jpg 300w\" sizes=\"(max-width: 690px) 100vw, 690px\" \/><\/a><\/strong><\/p>\n<p>For a list of publications by the members of NordCO<sub>2<\/sub>, see our <a href=\"https:\/\/site.uit.no\/nordco2\/publications\/\">Publications<\/a> page!<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Abstract A range of hitherto unexplored biomass\u2010derived chemicals have been evaluated as new sustainable solvents for a large variety of CO2\u2010based carboxylation reactions. Known biomass\u2010derived &hellip;<\/p>\n","protected":false},"author":514,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"ngg_post_thumbnail":0,"footnotes":""},"categories":[8],"tags":[],"class_list":["post-1257","post","type-post","status-publish","format-standard","hentry","category-research"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v28.8 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>New article from the Hopmann\/Bayer group - Nordic Consortium for CO2 Conversion<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/site.uit.no\/nordco2\/2020\/01\/14\/new-article-from-the-hopmann-bayer-group\/\" \/>\n<meta property=\"og:locale\" content=\"en_GB\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"New article from the Hopmann\/Bayer group - Nordic Consortium for CO2 Conversion\" \/>\n<meta property=\"og:description\" content=\"Abstract A range of hitherto unexplored biomass\u2010derived chemicals have been evaluated as new sustainable solvents for a large variety of CO2\u2010based carboxylation reactions. Known biomass\u2010derived &hellip;\" \/>\n<meta property=\"og:url\" content=\"https:\/\/site.uit.no\/nordco2\/2020\/01\/14\/new-article-from-the-hopmann-bayer-group\/\" \/>\n<meta property=\"og:site_name\" content=\"Nordic Consortium for CO2 Conversion\" \/>\n<meta property=\"article:published_time\" content=\"2020-01-14T16:28:40+00:00\" \/>\n<meta property=\"article:modified_time\" content=\"2024-10-11T10:26:55+00:00\" \/>\n<meta property=\"og:image\" content=\"https:\/\/site.uit.no\/nordco2\/wp-content\/uploads\/sites\/344\/2020\/04\/ezgif.com-gif-maker-2.jpg\" \/>\n<meta name=\"author\" content=\"joehh\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<meta name=\"twitter:label1\" content=\"Written by\" \/>\n\t<meta name=\"twitter:data1\" content=\"joehh\" \/>\n\t<meta name=\"twitter:label2\" content=\"Est. reading time\" \/>\n\t<meta name=\"twitter:data2\" content=\"1 minute\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\\\/\\\/schema.org\",\"@graph\":[{\"@type\":\"Article\",\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/2020\\\/01\\\/14\\\/new-article-from-the-hopmann-bayer-group\\\/#article\",\"isPartOf\":{\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/2020\\\/01\\\/14\\\/new-article-from-the-hopmann-bayer-group\\\/\"},\"author\":{\"name\":\"joehh\",\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/#\\\/schema\\\/person\\\/993cf3b27a956c23c8da21d29fe6bd7c\"},\"headline\":\"New article from the Hopmann\\\/Bayer group\",\"datePublished\":\"2020-01-14T16:28:40+00:00\",\"dateModified\":\"2024-10-11T10:26:55+00:00\",\"mainEntityOfPage\":{\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/2020\\\/01\\\/14\\\/new-article-from-the-hopmann-bayer-group\\\/\"},\"wordCount\":157,\"publisher\":{\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/#organization\"},\"image\":{\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/2020\\\/01\\\/14\\\/new-article-from-the-hopmann-bayer-group\\\/#primaryimage\"},\"thumbnailUrl\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/wp-content\\\/uploads\\\/sites\\\/344\\\/2020\\\/04\\\/ezgif.com-gif-maker-2.jpg\",\"articleSection\":[\"Research\"],\"inLanguage\":\"en-GB\"},{\"@type\":\"WebPage\",\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/2020\\\/01\\\/14\\\/new-article-from-the-hopmann-bayer-group\\\/\",\"url\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/2020\\\/01\\\/14\\\/new-article-from-the-hopmann-bayer-group\\\/\",\"name\":\"New article from the Hopmann\\\/Bayer group - 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