{"id":2978,"date":"2023-07-13T13:05:00","date_gmt":"2023-07-13T11:05:00","guid":{"rendered":"https:\/\/site.uit.no\/nordco2\/?p=2978"},"modified":"2024-10-11T12:19:45","modified_gmt":"2024-10-11T10:19:45","slug":"research-article-uit-5","status":"publish","type":"post","link":"https:\/\/site.uit.no\/nordco2\/2023\/07\/13\/research-article-uit-5\/","title":{"rendered":"Research Article: UiT"},"content":{"rendered":"\n<figure class=\"wp-block-image size-large\"><img decoding=\"async\" src=\"https:\/\/pubs.rsc.org\/en\/Image\/Get?imageInfo.ImageType=GA&amp;imageInfo.ImageIdentifier.ManuscriptID=D3SC01459B&amp;imageInfo.ImageIdentifier.Year=2023\" alt=\"graphical abstract\" \/><\/figure>\n\n\n\n<p class=\"wp-block-paragraph\"><strong>Title:<\/strong><br><a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2023\/sc\/d3sc01459b\" data-type=\"URL\" data-id=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2023\/sc\/d3sc01459b\">Comparative study of CO<sub>2<\/sub>\u00a0insertion into pincer supported palladium alkyl and aryl complexes<\/a><\/p>\n\n\n\n<p class=\"wp-block-paragraph\">Abstract:<br>The insertion of CO<small><sub>2<\/sub><\/small>\u00a0into metal alkyl bonds is a crucial elementary step in transition metal-catalyzed processes for CO<small><sub>2<\/sub><\/small>\u00a0utilization. Here, we synthesize pincer-supported palladium complexes of the type (<small><sup><em>t<\/em>Bu<\/sup><\/small>PBP)Pd(alkyl) (<small><sup><em>t<\/em>Bu<\/sup><\/small>PBP = B(NCH<small><sub>2<\/sub><\/small>P<small><sup><em>t<\/em><\/sup><\/small>Bu<small><sub>2<\/sub><\/small>)<small><sub>2<\/sub><\/small>C<small><sub>6<\/sub><\/small>H<small><sub>4<\/sub><sup>\u2212<\/sup><\/small>; alkyl = CH<small><sub>2<\/sub><\/small>CH<small><sub>3<\/sub><\/small>, CH<small><sub>2<\/sub><\/small>CH<small><sub>2<\/sub><\/small>CH<small><sub>3,<\/sub><\/small>\u00a0CH<small><sub>2<\/sub><\/small>C<small><sub>6<\/sub><\/small>H<small><sub>5<\/sub><\/small>, and CH<small><sub>2<\/sub><\/small>-4-OMe-C<small><sub>6<\/sub><\/small>H<small><sub>4<\/sub><\/small>) and (<small><sup><em>t<\/em>Bu<\/sup><\/small>PBP)Pd(C<small><sub>6<\/sub><\/small>H<small><sub>5<\/sub><\/small>) and compare the rates of CO<small><sub>2<\/sub><\/small>\u00a0insertion into the palladium alkyl bonds to form metal carboxylate complexes. Although, the rate constant for CO<small><sub>2<\/sub><\/small>\u00a0insertion into (<small><sup><em>t<\/em>Bu<\/sup><\/small>PBP)Pd(CH<small><sub>2<\/sub><\/small>CH<small><sub>3<\/sub><\/small>) is more than double the rate constant we previously measured for insertion into the palladium methyl complex (<small><sup><em>t<\/em>Bu<\/sup><\/small>PBP)Pd(CH<small><sub>3<\/sub><\/small>), insertion into (<small><sup><em>t<\/em>Bu<\/sup><\/small>PBP)Pd(CH<small><sub>2<\/sub><\/small>CH<small><sub>2<\/sub><\/small>CH<small><sub>3<\/sub><\/small>) occurs approximately one order of magnitude slower than (<small><sup><em>t<\/em>Bu<\/sup><\/small>PBP)Pd(CH<small><sub>3<\/sub><\/small>). CO<small><sub>2<\/sub><\/small>\u00a0insertion into the benzyl complexes (<small><sup><em>t<\/em>Bu<\/sup><\/small>PBP)Pd(CH<small><sub>2<\/sub><\/small>C<small><sub>6<\/sub><\/small>H<small><sub>5<\/sub><\/small>) and (<small><sup><em>t<\/em>Bu<\/sup><\/small>PBP)Pd(CH<small><sub>2<\/sub><\/small>-4-OMe-C<small><sub>6<\/sub><\/small>H<small><sub>4<\/sub><\/small>) is significantly slower than any of the n-alkyl complexes, and CO<small><sub>2<\/sub><\/small>\u00a0does not insert into the palladium phenyl bond of (<small><sup><em>t<\/em>Bu<\/sup><\/small>PBP)Pd(C<small><sub>6<\/sub><\/small>H<small><sub>5<\/sub><\/small>). While (<small><sup><em>t<\/em>Bu<\/sup><\/small>PBP)Pd(CH<small><sub>2<\/sub><\/small>CH<small><sub>3<\/sub><\/small>) and (<small><sup><em>t<\/em>Bu<\/sup><\/small>PBP)Pd(CH<small><sub>2<\/sub><\/small>CH<small><sub>2<\/sub><\/small>CH<small><sub>3<\/sub><\/small>) are resistant to \u03b2-hydride elimination, we were unable to synthesize complexes with\u00a0<em>n<\/em>-butyl, iso-propyl, and\u00a0<em>tert<\/em>-butyl ligands due to \u03b2-hydride elimination and an unusual reductive coupling, which involves the formation of new C\u2013B bonds. This reductive process also occurred for (<small><sup><em>t<\/em>Bu<\/sup><\/small>PBP)Pd(CH<small><sub>2<\/sub><\/small>C<small><sub>6<\/sub><\/small>H<small><sub>5<\/sub><\/small>) at elevated temperature and a related process involving the formation of a new H\u2013B bond prevented the isolation of (<small><sup><em>t<\/em>Bu<\/sup><\/small>PBP)PdH. DFT calculations provide insight into the relative rates of CO<small><sub>2<\/sub><\/small>\u00a0insertion and indicate that steric factors are critical. Overall, this work is one of the first comparative studies of the rates of CO<small><sub>2<\/sub><\/small>\u00a0insertion into different metal alkyl bonds and provides fundamental information that may be important for the development of new catalysts for CO<small><sub>2<\/sub><\/small>\u00a0utilization.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">Find a list of publications by\u00a0NordCO<sub>2<\/sub>\u00a0members on our\u00a0<a href=\"https:\/\/site.uit.no\/nordco2\/publications\/\">Publications<\/a>\u00a0page\u00a0\ud83d\ude42<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Title:Comparative study of CO2\u00a0insertion into pincer supported palladium alkyl and aryl complexes Abstract:The insertion of CO2\u00a0into metal alkyl bonds is a crucial elementary step in &hellip;<\/p>\n","protected":false},"author":514,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"image","meta":{"ngg_post_thumbnail":0,"footnotes":""},"categories":[8],"tags":[],"class_list":["post-2978","post","type-post","status-publish","format-image","hentry","category-research","post_format-post-format-image"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v28.8 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Research Article: UiT - Nordic Consortium for CO2 Conversion<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/site.uit.no\/nordco2\/2023\/07\/13\/research-article-uit-5\/\" \/>\n<meta property=\"og:locale\" content=\"en_GB\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Research Article: UiT - Nordic Consortium for CO2 Conversion\" \/>\n<meta property=\"og:description\" content=\"Title:Comparative study of CO2\u00a0insertion into pincer supported palladium alkyl and aryl complexes Abstract:The insertion of CO2\u00a0into metal alkyl bonds is a crucial elementary step in &hellip;\" \/>\n<meta property=\"og:url\" content=\"https:\/\/site.uit.no\/nordco2\/2023\/07\/13\/research-article-uit-5\/\" \/>\n<meta property=\"og:site_name\" content=\"Nordic Consortium for CO2 Conversion\" \/>\n<meta property=\"article:published_time\" content=\"2023-07-13T11:05:00+00:00\" \/>\n<meta property=\"article:modified_time\" content=\"2024-10-11T10:19:45+00:00\" \/>\n<meta property=\"og:image\" content=\"https:\/\/pubs.rsc.org\/en\/Image\/Get?imageInfo.ImageType=GA&amp;imageInfo.ImageIdentifier.ManuscriptID=D3SC01459B&amp;imageInfo.ImageIdentifier.Year=2023\" \/>\n<meta name=\"author\" content=\"joehh\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<meta name=\"twitter:label1\" content=\"Written by\" \/>\n\t<meta name=\"twitter:data1\" content=\"joehh\" \/>\n\t<meta name=\"twitter:label2\" content=\"Est. reading time\" \/>\n\t<meta name=\"twitter:data2\" content=\"2 minutes\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\\\/\\\/schema.org\",\"@graph\":[{\"@type\":\"Article\",\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/2023\\\/07\\\/13\\\/research-article-uit-5\\\/#article\",\"isPartOf\":{\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/2023\\\/07\\\/13\\\/research-article-uit-5\\\/\"},\"author\":{\"name\":\"joehh\",\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/#\\\/schema\\\/person\\\/993cf3b27a956c23c8da21d29fe6bd7c\"},\"headline\":\"Research Article: UiT\",\"datePublished\":\"2023-07-13T11:05:00+00:00\",\"dateModified\":\"2024-10-11T10:19:45+00:00\",\"mainEntityOfPage\":{\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/2023\\\/07\\\/13\\\/research-article-uit-5\\\/\"},\"wordCount\":347,\"publisher\":{\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/#organization\"},\"image\":{\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/2023\\\/07\\\/13\\\/research-article-uit-5\\\/#primaryimage\"},\"thumbnailUrl\":\"https:\\\/\\\/pubs.rsc.org\\\/en\\\/Image\\\/Get?imageInfo.ImageType=GA&amp;imageInfo.ImageIdentifier.ManuscriptID=D3SC01459B&amp;imageInfo.ImageIdentifier.Year=2023\",\"articleSection\":[\"Research\"],\"inLanguage\":\"en-GB\"},{\"@type\":\"WebPage\",\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/2023\\\/07\\\/13\\\/research-article-uit-5\\\/\",\"url\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/2023\\\/07\\\/13\\\/research-article-uit-5\\\/\",\"name\":\"Research Article: UiT - Nordic Consortium for CO2 Conversion\",\"isPartOf\":{\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/#website\"},\"primaryImageOfPage\":{\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/2023\\\/07\\\/13\\\/research-article-uit-5\\\/#primaryimage\"},\"image\":{\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/2023\\\/07\\\/13\\\/research-article-uit-5\\\/#primaryimage\"},\"thumbnailUrl\":\"https:\\\/\\\/pubs.rsc.org\\\/en\\\/Image\\\/Get?imageInfo.ImageType=GA&amp;imageInfo.ImageIdentifier.ManuscriptID=D3SC01459B&amp;imageInfo.ImageIdentifier.Year=2023\",\"datePublished\":\"2023-07-13T11:05:00+00:00\",\"dateModified\":\"2024-10-11T10:19:45+00:00\",\"breadcrumb\":{\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/2023\\\/07\\\/13\\\/research-article-uit-5\\\/#breadcrumb\"},\"inLanguage\":\"en-GB\",\"potentialAction\":[{\"@type\":\"ReadAction\",\"target\":[\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/2023\\\/07\\\/13\\\/research-article-uit-5\\\/\"]}]},{\"@type\":\"ImageObject\",\"inLanguage\":\"en-GB\",\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/2023\\\/07\\\/13\\\/research-article-uit-5\\\/#primaryimage\",\"url\":\"https:\\\/\\\/pubs.rsc.org\\\/en\\\/Image\\\/Get?imageInfo.ImageType=GA&amp;imageInfo.ImageIdentifier.ManuscriptID=D3SC01459B&amp;imageInfo.ImageIdentifier.Year=2023\",\"contentUrl\":\"https:\\\/\\\/pubs.rsc.org\\\/en\\\/Image\\\/Get?imageInfo.ImageType=GA&amp;imageInfo.ImageIdentifier.ManuscriptID=D3SC01459B&amp;imageInfo.ImageIdentifier.Year=2023\"},{\"@type\":\"BreadcrumbList\",\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/2023\\\/07\\\/13\\\/research-article-uit-5\\\/#breadcrumb\",\"itemListElement\":[{\"@type\":\"ListItem\",\"position\":1,\"name\":\"Home\",\"item\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/\"},{\"@type\":\"ListItem\",\"position\":2,\"name\":\"Research Article: UiT\"}]},{\"@type\":\"WebSite\",\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/#website\",\"url\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/\",\"name\":\"Nordic Consortium for CO2 Conversion\",\"description\":\"\",\"publisher\":{\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/#organization\"},\"potentialAction\":[{\"@type\":\"SearchAction\",\"target\":{\"@type\":\"EntryPoint\",\"urlTemplate\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/?s={search_term_string}\"},\"query-input\":{\"@type\":\"PropertyValueSpecification\",\"valueRequired\":true,\"valueName\":\"search_term_string\"}}],\"inLanguage\":\"en-GB\"},{\"@type\":\"Organization\",\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/#organization\",\"name\":\"Nordic Consortium for CO2 Conversion\",\"url\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/\",\"logo\":{\"@type\":\"ImageObject\",\"inLanguage\":\"en-GB\",\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/#\\\/schema\\\/logo\\\/image\\\/\",\"url\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/wp-content\\\/uploads\\\/sites\\\/344\\\/2018\\\/01\\\/cropped-logonewnordco2_2-2.png\",\"contentUrl\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/wp-content\\\/uploads\\\/sites\\\/344\\\/2018\\\/01\\\/cropped-logonewnordco2_2-2.png\",\"width\":174,\"height\":96,\"caption\":\"Nordic Consortium for CO2 Conversion\"},\"image\":{\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/#\\\/schema\\\/logo\\\/image\\\/\"}},{\"@type\":\"Person\",\"@id\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/#\\\/schema\\\/person\\\/993cf3b27a956c23c8da21d29fe6bd7c\",\"name\":\"joehh\",\"image\":{\"@type\":\"ImageObject\",\"inLanguage\":\"en-GB\",\"@id\":\"https:\\\/\\\/secure.gravatar.com\\\/avatar\\\/41b39828da26f7150fc97cb70bc12710fe106a864e4f01c116292a086677dd77?s=96&d=blank&r=g\",\"url\":\"https:\\\/\\\/secure.gravatar.com\\\/avatar\\\/41b39828da26f7150fc97cb70bc12710fe106a864e4f01c116292a086677dd77?s=96&d=blank&r=g\",\"contentUrl\":\"https:\\\/\\\/secure.gravatar.com\\\/avatar\\\/41b39828da26f7150fc97cb70bc12710fe106a864e4f01c116292a086677dd77?s=96&d=blank&r=g\",\"caption\":\"joehh\"},\"url\":\"https:\\\/\\\/site.uit.no\\\/nordco2\\\/author\\\/joehh\\\/\"}]}<\/script>\n<!-- \/ Yoast SEO plugin. -->","yoast_head_json":{"title":"Research Article: UiT - Nordic Consortium for CO2 Conversion","robots":{"index":"index","follow":"follow","max-snippet":"max-snippet:-1","max-image-preview":"max-image-preview:large","max-video-preview":"max-video-preview:-1"},"canonical":"https:\/\/site.uit.no\/nordco2\/2023\/07\/13\/research-article-uit-5\/","og_locale":"en_GB","og_type":"article","og_title":"Research Article: UiT - Nordic Consortium for CO2 Conversion","og_description":"Title:Comparative study of CO2\u00a0insertion into pincer supported palladium alkyl and aryl complexes Abstract:The insertion of CO2\u00a0into metal alkyl bonds is a crucial elementary step in &hellip;","og_url":"https:\/\/site.uit.no\/nordco2\/2023\/07\/13\/research-article-uit-5\/","og_site_name":"Nordic Consortium for CO2 Conversion","article_published_time":"2023-07-13T11:05:00+00:00","article_modified_time":"2024-10-11T10:19:45+00:00","og_image":[{"url":"https:\/\/pubs.rsc.org\/en\/Image\/Get?imageInfo.ImageType=GA&amp;imageInfo.ImageIdentifier.ManuscriptID=D3SC01459B&amp;imageInfo.ImageIdentifier.Year=2023","type":"","width":"","height":""}],"author":"joehh","twitter_card":"summary_large_image","twitter_misc":{"Written by":"joehh","Est. reading time":"2 minutes"},"schema":{"@context":"https:\/\/schema.org","@graph":[{"@type":"Article","@id":"https:\/\/site.uit.no\/nordco2\/2023\/07\/13\/research-article-uit-5\/#article","isPartOf":{"@id":"https:\/\/site.uit.no\/nordco2\/2023\/07\/13\/research-article-uit-5\/"},"author":{"name":"joehh","@id":"https:\/\/site.uit.no\/nordco2\/#\/schema\/person\/993cf3b27a956c23c8da21d29fe6bd7c"},"headline":"Research Article: UiT","datePublished":"2023-07-13T11:05:00+00:00","dateModified":"2024-10-11T10:19:45+00:00","mainEntityOfPage":{"@id":"https:\/\/site.uit.no\/nordco2\/2023\/07\/13\/research-article-uit-5\/"},"wordCount":347,"publisher":{"@id":"https:\/\/site.uit.no\/nordco2\/#organization"},"image":{"@id":"https:\/\/site.uit.no\/nordco2\/2023\/07\/13\/research-article-uit-5\/#primaryimage"},"thumbnailUrl":"https:\/\/pubs.rsc.org\/en\/Image\/Get?imageInfo.ImageType=GA&amp;imageInfo.ImageIdentifier.ManuscriptID=D3SC01459B&amp;imageInfo.ImageIdentifier.Year=2023","articleSection":["Research"],"inLanguage":"en-GB"},{"@type":"WebPage","@id":"https:\/\/site.uit.no\/nordco2\/2023\/07\/13\/research-article-uit-5\/","url":"https:\/\/site.uit.no\/nordco2\/2023\/07\/13\/research-article-uit-5\/","name":"Research Article: UiT - Nordic Consortium for CO2 Conversion","isPartOf":{"@id":"https:\/\/site.uit.no\/nordco2\/#website"},"primaryImageOfPage":{"@id":"https:\/\/site.uit.no\/nordco2\/2023\/07\/13\/research-article-uit-5\/#primaryimage"},"image":{"@id":"https:\/\/site.uit.no\/nordco2\/2023\/07\/13\/research-article-uit-5\/#primaryimage"},"thumbnailUrl":"https:\/\/pubs.rsc.org\/en\/Image\/Get?imageInfo.ImageType=GA&amp;imageInfo.ImageIdentifier.ManuscriptID=D3SC01459B&amp;imageInfo.ImageIdentifier.Year=2023","datePublished":"2023-07-13T11:05:00+00:00","dateModified":"2024-10-11T10:19:45+00:00","breadcrumb":{"@id":"https:\/\/site.uit.no\/nordco2\/2023\/07\/13\/research-article-uit-5\/#breadcrumb"},"inLanguage":"en-GB","potentialAction":[{"@type":"ReadAction","target":["https:\/\/site.uit.no\/nordco2\/2023\/07\/13\/research-article-uit-5\/"]}]},{"@type":"ImageObject","inLanguage":"en-GB","@id":"https:\/\/site.uit.no\/nordco2\/2023\/07\/13\/research-article-uit-5\/#primaryimage","url":"https:\/\/pubs.rsc.org\/en\/Image\/Get?imageInfo.ImageType=GA&amp;imageInfo.ImageIdentifier.ManuscriptID=D3SC01459B&amp;imageInfo.ImageIdentifier.Year=2023","contentUrl":"https:\/\/pubs.rsc.org\/en\/Image\/Get?imageInfo.ImageType=GA&amp;imageInfo.ImageIdentifier.ManuscriptID=D3SC01459B&amp;imageInfo.ImageIdentifier.Year=2023"},{"@type":"BreadcrumbList","@id":"https:\/\/site.uit.no\/nordco2\/2023\/07\/13\/research-article-uit-5\/#breadcrumb","itemListElement":[{"@type":"ListItem","position":1,"name":"Home","item":"https:\/\/site.uit.no\/nordco2\/"},{"@type":"ListItem","position":2,"name":"Research Article: UiT"}]},{"@type":"WebSite","@id":"https:\/\/site.uit.no\/nordco2\/#website","url":"https:\/\/site.uit.no\/nordco2\/","name":"Nordic Consortium for CO2 Conversion","description":"","publisher":{"@id":"https:\/\/site.uit.no\/nordco2\/#organization"},"potentialAction":[{"@type":"SearchAction","target":{"@type":"EntryPoint","urlTemplate":"https:\/\/site.uit.no\/nordco2\/?s={search_term_string}"},"query-input":{"@type":"PropertyValueSpecification","valueRequired":true,"valueName":"search_term_string"}}],"inLanguage":"en-GB"},{"@type":"Organization","@id":"https:\/\/site.uit.no\/nordco2\/#organization","name":"Nordic Consortium for CO2 Conversion","url":"https:\/\/site.uit.no\/nordco2\/","logo":{"@type":"ImageObject","inLanguage":"en-GB","@id":"https:\/\/site.uit.no\/nordco2\/#\/schema\/logo\/image\/","url":"https:\/\/site.uit.no\/nordco2\/wp-content\/uploads\/sites\/344\/2018\/01\/cropped-logonewnordco2_2-2.png","contentUrl":"https:\/\/site.uit.no\/nordco2\/wp-content\/uploads\/sites\/344\/2018\/01\/cropped-logonewnordco2_2-2.png","width":174,"height":96,"caption":"Nordic Consortium for CO2 Conversion"},"image":{"@id":"https:\/\/site.uit.no\/nordco2\/#\/schema\/logo\/image\/"}},{"@type":"Person","@id":"https:\/\/site.uit.no\/nordco2\/#\/schema\/person\/993cf3b27a956c23c8da21d29fe6bd7c","name":"joehh","image":{"@type":"ImageObject","inLanguage":"en-GB","@id":"https:\/\/secure.gravatar.com\/avatar\/41b39828da26f7150fc97cb70bc12710fe106a864e4f01c116292a086677dd77?s=96&d=blank&r=g","url":"https:\/\/secure.gravatar.com\/avatar\/41b39828da26f7150fc97cb70bc12710fe106a864e4f01c116292a086677dd77?s=96&d=blank&r=g","contentUrl":"https:\/\/secure.gravatar.com\/avatar\/41b39828da26f7150fc97cb70bc12710fe106a864e4f01c116292a086677dd77?s=96&d=blank&r=g","caption":"joehh"},"url":"https:\/\/site.uit.no\/nordco2\/author\/joehh\/"}]}},"_links":{"self":[{"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/posts\/2978","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/users\/514"}],"replies":[{"embeddable":true,"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/comments?post=2978"}],"version-history":[{"count":1,"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/posts\/2978\/revisions"}],"predecessor-version":[{"id":2979,"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/posts\/2978\/revisions\/2979"}],"wp:attachment":[{"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/media?parent=2978"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/categories?post=2978"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/site.uit.no\/nordco2\/wp-json\/wp\/v2\/tags?post=2978"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}